SafetyNet #4 - Partial List of Incompatible Chemicals
The following list is to be used only as a guide. Specific incompatibilities are listed in the Material Safety Data Sheets. Consult Betherick’s Handbook of Reactive Chemical Hazards (Urben, P.G.; 6th Ed.; Butterworth-Heinemann: London, 200; book and CD-ROM) for an extensive listing and thorough discussion of chemical incompatibilities.
Example of Incompatible Chemicals*
|
Chemical: |
Incompatible With: |
|
Acetic acid |
Oxidizing agents, e.g., chromic acid, nitric acid, hydroxyl compounds, ethylene glycol, perchloric acid, peroxides, permanganates |
|
Acetone |
Nitric acid and sulfuric acid, other oxidizing agents |
|
Acetylene |
Chlorine, bromine, copper, fluorine, silver, mercury |
|
Alkali and alkaline earth metals (such as powdered aluminum or magnesium, calcium, lithium, sodium, potassium) |
Water, carbon tetrachloride, other chlorinated hydrocarbon compounds, carbon dioxide, halogens |
|
Ammonia (anhydrous) |
Mercury (e.g., in manometers), chlorine, calcium hypochlorite, iodine, bromine, hydrofluoric acid |
|
Ammonium nitrate |
Acids, powdered metals, flammable liquids, chlorates, nitrites, sulfur, finely divided organic or combustible materials |
|
Aniline |
Nitric acid, hydrogen peroxide |
|
Arsenical materials |
Reducing agents |
|
Azides |
Acids |
|
Bromine |
See chlorine |
|
Calcium oxide |
Water |
|
Carbon (activated) |
Calcium hypochlorite, other oxidizing agents |
|
Chlorates |
Ammonium salts, acids, powdered metals, sulfur, finely divided organic or combustible materials |
|
Chlorine |
Ammonia, acetylene, butadiene, butane, methane, propane (or other petroleum gases), hydrogen, sodium carbide, benzene, finely divided metals, turpentine |
|
Chlorine dioxide |
Ammonia, methane, phosphine, hydrogen sulfide |
|
Chromium trioxide (chromic acid) |
Acetic acid, naphthalene, camphor, glycerol, alcohol, flammable liquids |
|
Copper |
Acetylene, hydrogen peroxide |
|
Cyanides |
Acids |
|
Flammable liquids |
Ammonium nitrate, chromic acid, hydrogen peroxide, nitric acid, sodium peroxide, halogens |
|
Hydrocarbons (e.g., butane, propane, benzene) |
Fluorine, chlorine, bromine, chromic acid, sodium peroxide, other oxidizing agents |
|
Hydrocyanic acid (anhydrous) |
Alkali |
|
Hydrofluoric acid |
Potassium permanganate, sulfuric acid |
|
Hydrogen sulfide |
Metal oxides, powdered copper, oxidizing gases |
|
Hypochlorites |
Acids, activated carbon, ammonia |
|
Iodine |
Acetylene, ammonia (aqueous or anhydrous), hydrogen |
|
Mercury |
Acetylene, fulminic acid, ammonia |
|
Nitrates |
Powdered metals and non-metals, metal sulfides, flammable/combustible liquids |
|
Nitric acid |
Acetic acid, aniline, chromic acid, hydrocyanic acid, hydrogen sulfide, flammable liquids and gases, copper, brass, heavy metals, alkalis |
|
Nitrites |
Ammonium salts, amides, phosphides, reducing agents |
|
Nitroparaffins |
Acids, bases, amines, halides |
|
Oxalic acid |
Silver, chlorites, urea |
|
Oxygen |
Oils, grease, hydrogen, and other reducing agents, including flammable liquids, solids or gases |
|
Perchlorates |
See Chlorates |
|
Perchloric acid |
Reducing agents such as acetic anhydride, bismuth and its alloys, alcohols, paper, wood, grease, oils |
|
Phosphorous (white) |
Air, oxygen, alkalis, halogens, halogen oxides, oxidizing agents |
|
Potassium |
Carbon tetrachloride, carbon dioxide, water |
|
Potassium permanganate |
Glycerol, ethylene glycol, benzaldehyde, other reducing agents, sulfuric acid |
|
Sodium |
Carbon tetrachloride, carbon dioxide, water |
|
Sodium peroxide |
Ethyl and methyl alcohol, glacial acetic acid, acetic anhydride, benzaldehyde, carbon disulfide, glycerin, ethylene glycol, ethyl acetate, methyl acetate, furfural |
|
Sulfides |
Acids |
|
Sulfuric acid |
Permanganates, water, aqueous solutions, reducing agents, chlorates, perchlorates, nitric acid |
*Reference: Safety in Academic Chemistry Laboratories Volume 1. Published by the American Chemical Society, Committee on Chemical Safety: 7th Edition, Appendix IV. Reprinted by permission..
For additional information, contact your EH&S Safety Advisor, EH&S at 530-752-1493 or ehsdesk@ucdavis.edu.
Reviewed/Revised. 05/2007
DMD
